Chapter I discusses a new generation of e-learning development, based on synchronous groupware applications integration, providing improved interactivity and pro-human relations, allows richer training experiences far beyond a virtual classroom. Despite WWW service evolution, e-conferencing multimedia applications remain “killer applications” and insensitive to resources degradation, in fact, the quality of service (QoS) provided by the network is still a limitation impairing their performance. Such applications have found in multicast technology an ally contributing for their efficient implementation and scalability. Additionally, considering QoS as design goal at application level becomes crucial for groupware development, enabling QoS proactivity to applications. Congregating these technological contributions, an adaptive platform has been developed integrating public domain multicast tools, applied to a Web-based distance learning system. The system is user-centered (e-student), aiming at good pedagogical practices and proactive usability for multimedia and network resources. The services provided, including QoS adapted interactive multimedia multicast conferences (MMC), are fully integrated and transparent to end-users. QoS adaptation, when treated systematically in tolerant real-time applications, denotes advantages in group scalability and QoS sustainability in heterogeneous and unpredictable environments such as the Internet.